Regioselective bromination of quinopimaric acid derivatives

被引：0
|
作者：
I. E. Smirnova
O. B. Kazakova
E. V. Tret’yakova
L. V. Spirikhin
I. V. Glukhov
Yu. V. Nelyubina
机构：
[1] Russian Academy of Sciences,Institute of Organic Chemistry, Ufa Research Center
[2] Russian Academy of Sciences,Nesmeyanov Institute of Organometallic Compounds
来源：
Russian Journal of Organic Chemistry | 2010年 / 46卷
关键词：
Acid Methyl Ester; Abietic Acid; Dehydroabietic Acid; Methyl Carbon Atom; Molecular Bromine;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Regioselective bromination of 14β-hydroxydihydroquinopimaric acid methyl ester in acetic acid and methanol gave the corresponding 16S-bromo-, 19R-bromo-, and 16S,19R-dibromo-14β,20-epoxy derivatives whose structure was determined by X-ray analysis and NMR spectroscopy. The reactions of 16S-bromo ketones with thiourea afforded 2,1,3-thiadiazoles fused to diterpene fragment.
引用
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页码：1135 / 1139
页数：4
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