Catalytic activity of MnTUD-1 for liquid phase oxidation of ethylbenzene with tert-butyl hydroperoxide

被引：0

作者：

Gaffar Imran

Muthusamy Poomalai Pachamuthu

Rajamanickam Maheswari

Anand Ramanathan

S. J. Sardhar Basha

机构：

[1] Anna University,Department of Chemistry

[2] The University of Kansas,Center for Environmentally Beneficial Catalysis (CEBC)

[3] Anna University of Technology Madurai,Department of Chemistry

来源：

Journal of Porous Materials | 2012年 / 19卷

关键词：

Manganese; TUD-1; Mesoporous; Ethylbenzene; Oxidation; TBHP;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Manganese was incorporated into silica matrix of TUD-1 using tetraethylene glycol (TEG) as the template. Three samples with Si/Mn ratio of 115, 44 and 18 were prepared and characterized by various techniques. MnTUD-1 is shown to be mesoporous with tetrahedrally coordinated Mn when Si/Mn = 115; and nano-particles of manganese oxides are visible at higher loading of manganese (Si/Mn = 44 and 18). The catalytic activity of MnTUD-1 was explored in the liquid-phase oxidation of ethylbenzene with tert-butylhydroperoxide (TBHP) as oxidant. Influence of various reaction parameters such as time, Si/Mn ratio, oxidant and solvent were studied. Finally the catalytic activity also compared with well-known microporous and mesoporous catalysts like MnAlPO-5, Mn containing MCM-41, MCM-48 and SBA-15.

引用

页码：677 / 682

页数：5

共 50 条

[41] TETRABROMOOXOMOLYBDATE(V) COMPLEX - THE CATALYTIC REACTIVITY FOR THE REACTION OF TERT-BUTYL HYDROPEROXIDE
KURUSU, Y
MASUYAMA, Y
SAITA, M
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (03) : 1065 - 1066
[42] HALOGEN SUBSTITUENT EFFECTS ON THE CATALYTIC ACTIVITY OF IRON PORPHYRIN COMPLEXES FOR THE DECOMPOSITION OF TERT-BUTYL HYDROPEROXIDE
LYONS, JE
ELLIS, PE
MYERS, HK
WAGNER, RW
JOURNAL OF CATALYSIS, 1993, 141 (01) : 311 - 315
[43] Catalytic system based on triphenylantimony and tert-butyl hydroperoxide for the Heck reaction
Moiseev, DV
Gushchin, AV
Morugova, VA
Dodonov, VA
RUSSIAN CHEMICAL BULLETIN, 2003, 52 (09) : 2081 - 2082
[44] Solvent effect on oxidation of 1,3,5-triphenylverdazyl with tert-butyl hydroperoxide
Buzulukov, VI
Devyatkina, SY
Zhivechkova, LA
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 1999, 69 (12) : 1936 - 1938
[45] Oxidation of β-dicarbonyl compounds with tert-butyl hydroperoxide in the presence of vanadyl acetylacetonate
Stepovik, L. P.
Gulenova, M. V.
Kalacheva, I. A.
Potkina, A. Yu.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2011, 81 (03) : 550 - 558
[46] Oxidation of saturated hydrocarbons with tert-butyl hydroperoxide catalyzed by manganese complexes
Shul'pin, GB
PETROLEUM CHEMISTRY, 2001, 41 (06) : 405 - 412
[47] Iron-catalyzed benzylic oxidation with aqueous tert-butyl hydroperoxide
Nakanishi, Masafumi
Bolm, Carsten
ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (06) : 861 - 864
[48] BENZYLIC OXIDATION USING TERT-BUTYL HYDROPEROXIDE IN THE PRESENCE OF CHROMIUM HEXACARBONYL
PEARSON, AJ
HAN, GR
JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (15): : 2791 - 2792
[49] Bismuth(III) Oxide Catalyzed Oxidation of Alcohols with tert-Butyl Hydroperoxide
Malik, Payal
Chakraborty, Debashis
SYNTHESIS-STUTTGART, 2010, (21): : 3736 - 3740
[50] Manganese(II) β-diketonate catalyzed oxidation of cyclohexane by tert-butyl hydroperoxide
Tembe, GL
Ganeshpure, PA
Satish, S
REACTION KINETICS AND CATALYSIS LETTERS, 1998, 63 (02): : 385 - 389

← 1 2 3 4 5 →