The AC Stark Effect, Time-Dependent Born–Oppenheimer Approximation, and Franck–Condon Factors

被引：0
|
作者：
George A. Hagedorn
Vidian Rousse
Steven W. Jilcott
机构：
[1] Virginia Polytechnic Institute and State University,Department of Mathematics and Center for Statistical Mechanics and Mathematical Physics
[2] Université de Cergy-Pontoise,Département de Mathématiques
[3] BAE Systems Advanced Information Technology,undefined
来源：
Annales Henri Poincaré | 2006年 / 7卷
关键词：
Wave Packet; Vibrational State; High Order Correction; Vertical Transition; Electron Energy Level;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
We study the quantum mechanics of a simple molecular system that is subject to a laser pulse. We model the laser pulse by a classical oscillatory electric field, and we employ the Born–Oppenheimer approximation for the molecule. We compute transition amplitudes to leading order in the laser strength. These amplitudes contain Franck–Condon factors that we compute explicitly to leading order in the Born–Oppenheimer parameter.
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页码：1065 / 1083
页数：18
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