Hydroethoxycarbonylation of α-olefins at low pressure of carbon(II) oxide in the presence of the PdCl2(PPh3)2–PPh3–AlCl3 system

被引：0
|
作者：
Kh. A. Suerbaev
N. Zh. Kudaibergenov
A. Vavasori
机构：
[1] Al-Farabi Kazakh National University,
[2] Ca’Foscari University of Venice,undefined
来源：
Russian Journal of General Chemistry | 2017年 / 87卷
关键词：
palladium; triphenylphosphine; aluminum chloride; olefins; carbonylation;
D O I：
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中图分类号：
学科分类号：
摘要：
High catalytic activity of the PdCl2(PPh3)2–PPh3–AlCl3 system containing AlCl3 as promotor has been demonstrated in the reaction of hydroethoxycarbonylation of hexene-1 and octene-1 at low pressure of carbon(II) oxide (≤25 atm). The reaction yields linear and branched products. The optimal conditions of the process have been elaborated. The target products yield is 84.6–93.8%.
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页码：707 / 712
页数：5
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