Hydroethoxycarbonylation of α-Olefins at Low Pressure of Carbon(II) Oxide in the Presence of the PdCl2(PPh3)2-PPh3-AlCl3 System

被引：14
|
作者：
Suerbaev, Kh. A. [1 ]
Kudaibergenov, N. Zh. [1 ]
Vavasori, A. [2 ]
机构：
[1] Al Farabi Kazakh Natl Univ, Ul Tole Bi 96A, Alma Ata 050012, Kazakhstan
[2] CaFoscari Univ Venice, Venice, Italy
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2017年 / 87卷 / 04期
关键词：
palladium; triphenylphosphine; aluminum chloride; olefins; carbonylation; LEWIS-ACID; CATALYST; METHOXYCARBONYLATION; HYDROESTERIFICATION; CARBONYLATION; ETHYLENE; COMPLEX;
D O I：
10.1134/S1070363217040089
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
High catalytic activity of the PdCl2(PPh3)(2)-PPh3-AlCl3 system containing AlCl3 as promotor has been demonstrated in the reaction of hydroethoxycarbonylation of hexene-1 and octene-1 at low pressure of carbon(II) oxide (<= 25 atm). The reaction yields linear and branched products. The optimal conditions of the process have been elaborated. The target products yield is 84.6-93.8%.
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页码：707 / 712
页数：6
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