Effect of sulfurization temperature on the property of Cu2ZnSnS4 thin film by eco-friendly nanoparticle ink method

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作者
Wei Wang
Honglie Shen
Hanyu Yao
Huirong Shang
ZhengXia Tang
Yufang Li
机构
[1] Jinling Institute of Technology,School of Material Engineering
[2] Nanjing University of Aeronautics and Astronautics,College of Materials Science and Technology, Jiangsu Provincial Key Laboratory of Materials and Technology for Energy Conversion
来源
Applied Physics A | 2017年 / 123卷
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摘要
Cu2ZnSnS4 (CZTS) thin films were fabricated by a low-cost nanoparticle ink method. The eco-friendly hydrophilic CZTS nanoparticles were mixed with low-cost n-propanol to form nanoparticle ink. To improve crystallinity and remove oxygen element, the CZTS thin films were sulfurized further. The effects of sulfurization temperature on the structure, morphologies, and photovoltaic performances of CZTS thin films were investigated. The results showed that the crystallinity of CZTS thin film was improved with increasing sulfurization temperature. The surface morphology studies demonstrated the formation of compact and homogenous CZTS thin film at a sulfurization temperature of 600 °C. By optimizing thickness of CZTS thin film, the CZTS thin-film solar cell with an optimal efficiency of 2.1% was obtained.
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