Boric acid catalyzed efficient synthesis of symmetrical N,N′-alkylidene bisamides

被引:0
|
作者
G. Harichandran
S. David Amalraj
P. Shanmugam
机构
[1] University of Madras,Department of Polymer Science
[2] Central Leather Research Institute,Organic Chemistry Laboratory
关键词
-Alkylidene bisamides; Amides; Aldehydes; Boric acid;
D O I
暂无
中图分类号
学科分类号
摘要
Symmetrical N,N′-alkylidene bisamides were synthesized in excellent yield by condensation of aromatic aldehydes and amides in the presence of boric acid as a catalyst under thermal and neat microwave irradiation conditions. It is the first successful report of boric acid has been used as Lewis acid catalyst for the preparation of symmetrical N,N′-alkylidene bisamides. The remarkable advantages offered by this method are green catalyst, mild reaction condition, simple procedure, fast reaction and moderate to good yield of products.
引用
收藏
页码:298 / 305
页数:7
相关论文
共 50 条
  • [21] IMPROVED SYNTHESIS OF SYMMETRICAL N,N'-ALKYLIDENE-BIS-AMIDES
    GILBERT, EE
    SYNTHESIS-INTERNATIONAL JOURNAL OF METHODS IN SYNTHETIC ORGANIC CHEMISTRY, 1972, (01): : 30 - &
  • [22] Graphene oxide anchored with sulfonic acid-functionalized glycerin: production, characterization and catalytic performance for the synthesis of N,N′-alkylidene bisamides
    Seham Naeim-Fallahiyeh
    Esmael Rostami
    Habibeh Golchaman
    Soheila Kaman-Torki
    Research on Chemical Intermediates, 2020, 46 : 4141 - 4153
  • [23] AN EFFICIENT SYNTHESIS OF N,N'-SUBSTITUTED SYMMETRICAL DIAMINES
    VAULTIER, M
    CARBONI, B
    MARTINEZFRESNEDA, P
    SYNTHETIC COMMUNICATIONS, 1992, 22 (05) : 665 - 671
  • [24] A Nanostructured Organic-Inorganic Hybrid Material: Preparation, Characterization and Catalytic Performance for the Synthesis of N,N′-Alkylidene Bisamides
    Zare, Abdolkarim
    Khanivar, Roghayyeh
    Irannejad-Gheshlaghchaei, Navid
    Beyzavi, M. Hassan
    CHEMISTRYSELECT, 2019, 4 (13): : 3953 - 3960
  • [25] Efficient Synthesis of Symmetrical Bisamides from Aldehydes and Amides Catalyzed by Silica-Bonded S-Sulfonic Acid Nanoparticles
    Tajbakhsh, Mahmood
    Hosseinzadeh, Rahman
    Alinezhad, Heshmatollah
    Rezaee, Parizad
    SYNTHETIC COMMUNICATIONS, 2013, 43 (17) : 2370 - 2379
  • [26] Producing, characterizing and utilizing a novel magnetic catalyst to promote construction of N,N'-alkylidene bisamides
    Karimi, Amir Hosain
    Hekmat-Ara, Ali
    Zare, Abdolkarim
    Barzegar, Marziyeh
    Khanivar, Roghayyeh
    Sadeghi-Takallo, Masoud
    EURASIAN CHEMICAL COMMUNICATIONS, 2021, 3 (06): : 360 - 368
  • [27] Synthesis and Cytotoxic Activity of N,N′-(Arylmethylene)bisamides
    Uenishi, Jun'ichi
    Hirano, Hirokazu
    Ueda, Tsuyoshi
    Hoshiya, Naoyuki
    Ii, Hiromi
    Yoshiki, Tatsuhiro
    SYNTHESIS-STUTTGART, 2015, 47 (19): : 2976 - 2984
  • [28] Synthesis, characterization and application of nano-N,N,N′,N′-tetramethyl-N-(silica-n-propyl)-N′-sulfo-ethane-1,2-diaminium chloride as a highly efficient catalyst for the preparation of N,N′-alkylidene bisamides
    Abdolkarim Zare
    Masoud Sadeghi-Takallo
    Mostafa Karami
    Alireza Kohzadian
    Research on Chemical Intermediates, 2019, 45 : 2999 - 3018
  • [29] Synthesis, characterization and application of nano-N,N,N′,N′-tetramethyl-N-(silica-n-propyl)-N′-sulfo-ethane-1,2-diaminium chloride as a highly efficient catalyst for the preparation of N,N′-alkylidene bisamides
    Zare, Abdolkarim
    Sadeghi-Takallo, Masoud
    Karami, Mostafa
    Kohzadian, Alireza
    RESEARCH ON CHEMICAL INTERMEDIATES, 2019, 45 (05) : 2999 - 3018
  • [30] Boric acid-catalyzed n-acylation of sulfoximines
    Harmata, Michael
    Garimallaprabhakaran, Aswin K.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238