Crystal Structure of the Azido-Bridged Copper(II) Complex [Cu2L2(μ1,1-N3)2] Based on the 2-[(3-Amino-2,2-Dimethylpropylimino)-Methyl]-4-Bromophenol Schiff Base Ligand

被引：0
|
作者：
A. Ghaemi
B. Keyvani
K. Fayyazi
H. A. Rudbari
机构：
[1] Islamic Azad University,Department of Chemistry, Saveh Branch
[2] University of Isfahan,Department of Chemistry
来源：
Journal of Structural Chemistry | 2018年 / 59卷
关键词：
synthesis; Schiff base ligand; copper(II); crystal structure; 2-[(3-amino-2,2-dimethylpropylimino)-methyl]-4-bromophenol; azido-bridged; X-ray diffraction analysis;
D O I：
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中图分类号：
学科分类号：
摘要：
New end-on azido-bridged dinuclear copper(II) complex [Cu2L2(μ1,1-N3)2] (I) (HL = 2-[(3-amino-2,2-dimethylpropylimino)-methyl]-4-bromophenol) is synthesized and characterized by the elemental analysis and FT-IR spectroscopy. The crystal structure of I is determined by X-ray diffraction. The crystal of I is monoclinic, space group P21/c, a = 10.7926(4) Å, b = 12.4222(4) Å, c = 11.0894(4) Å, β = 100.085(2)°, V = 1463.76(9) Å3, Z = 2. The crystal structure shows that the structure contains [Cu2L2(μ1,1-N3)2] units joined together by intermolecular H-bonding interactions to form a 2D rectangular grid.
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页码：1176 / 1180
页数：4
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