Crystal Structure, and Luminescent Property of the Zinc(II) Complex Based on 2-Hydroxynaphthaldehyde

被引:0
|
作者
X.-Y. Dong
Sh.-Sh. Zheng
Y.-J. Dong
J.-L. Meng
W.-K. Dong
机构
[1] Lanzhou Jiaotong University,School of Chemical and Biological Engineering
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关键词
Salamo-type bisoxime compound; Zn(II) complex; synthesis; crystal structure; luminescent property;
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学科分类号
摘要
A new trinuclear Zn(II) complex [(ZnL)2(OAc)2Zn]·2THF with a Salamo-type bisoxime ligand H2L (2,2′-[ethylenedioxybis(nitrilomethylidyne)]dinaphthol) is synthesized and structurally characterized. The luminescence study demonstrates that the Salamo-type ligand exhibits a good antennae effect with respect to the Zn(II) ion due to an efficient intersystem crossing and ligand-to-metal energy transfer. From a more general perspective, this work opens interesting perspectives for the development of efficient luminescent stains to obtain a novel luminescent Zn(II) complex with Salamo-type derivatives.
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页码:981 / 987
页数:6
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