Kinetics of carbon monoxide methanation on nickel catalysts

被引：0
|
作者：
Luu Cam Loc
Nguyen Manh Huan
N. A. Gaidai
Ho Si Thoang
Yu. A. Agafonov
N. V. Nekrasov
A. L. Lapidus
机构：
[1] Vietnamese Academy of Science and Technology,Institute of Chemical Technology
[2] Russian Academy of Sciences,Zelinsky Institute of Organic Chemistry
来源：
Kinetics and Catalysis | 2012年 / 53卷
关键词：
NiAl; Nickel Catalyst; Slow Step; Methanation Reaction; Reaction Mixture Component;
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摘要：
The kinetics of CO methanation in excess H2 on CaO- and CeO2-doped nickel catalysts supported on Al2O3 and TiO2 was studied at atmospheric pressure in a temperature range of 180–240°C. It was found that the same rational fractional rate equation corresponding to the reaction taking place at high surface coverages, is valid for all of the catalysts. The activity of nickel catalysts in the methanation reaction and their adsorption capacity with respect to reaction mixture components depend on the nature of the support and dopants.
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页码：384 / 394
页数：10
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