Photoinduced C-H direct arylation of unactivated arenes

被引:0
|
作者
Jian Kan
Shijun Huang
Huaiqing Zhao
Jin Lin
Weiping Su
机构
[1] Chinese Academy of Sciences,State Key Laboratory of Structural Chemistry; Fujian Institute of Research on the Structure of Matter
来源
Science China Chemistry | 2015年 / 58卷
关键词
C-H bond activation; photoinduced; free radical; aryl iodide;
D O I
暂无
中图分类号
学科分类号
摘要
Two general protocols have been developed for the photoinduced, metal-free direct arylation of unactivated arenes with aryl iodide. Both methods gave good to excellent yields for most substrates. Notably, the C-F bond in method A and the C-F, C-Cl, and C-Br bonds in method B could survive the arylation reaction. These methods offered excellent options for syntheses of biaryls.
引用
收藏
页码:1329 / 1333
页数:4
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