Kinetics and Stereoselectivity in Gas-Phase Hydrogenation of Alkylbenzenes Over Ni/Al2O3

被引:0
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作者
Dmitry Yu. Murzin
Stefan Smeds
Tapio Salmi
机构
[1] Åbo Akademi,Laboratory of Industrial Chemistry, Process Chemistry Group
关键词
Alkylbenzenes; hydrogenation; nickel; kinetics; stereochemistry;
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摘要
Experimental data on gas-phase hydrogenation of several alkylbenzenes (toluene, ethlylbenzene, o-, m-, p-xylenes, mesitylene) over nickel catalyst are summarized. Rate dependence as a function of the chemical nature of substituent and position in the aromatic ring is discussed. The stereochemical distribution for dialkylbenzene and trialkylbenzene is addressed.
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页码:47 / 54
页数:7
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