Catalytic Transfer Dehydrogenation of Geraniol to Geranial Over Palladium and Copper Supported Catalysts

被引：0
|
作者：
Thierry Gerez
Michèle Besson
Catherine Pinel
Jean-Michel Joerger
Vivien Henryon
机构：
[1] IRCELYON,
[2] Institut de recherches sur la catalyse et l’environnement de Lyon,undefined
[3] UMR5256 CNRS-Université Lyon1,undefined
[4] ACTIVATION,undefined
来源：
Topics in Catalysis | 2014年 / 57卷
关键词：
Hydrogen transfer; Heterogeneous catalysis; Copper; Allylic alcohol; Geraniol; Styrene;
D O I：
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中图分类号：
学科分类号：
摘要：
Dehydrogenation of geraniol into geranial in the presence of a hydrogen acceptor (alkene) was studied. Supported palladium catalysts were not suitable for this transformation, but supported copper catalysts showed promising results at 150 °C; selectivity to the expected geranial was strongly dependent on the support and the calcinations/reduction procedure (>50 % in the presence of Mg–La hydrotalcite-supported copper).
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页码：1498 / 1504
页数：6
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