Study of methanol steam reforming and ethanol conversion in conventional and membrane reactors

被引：0
|
作者：
A. A. Lytkina
A. B. Ilin
A. B. Yaroslavtsev
机构：
[1] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis
来源：
Petroleum Chemistry | 2016年 / 56卷
关键词：
membrane catalysis; NASICON; methanol steam reforming; ethanol conversion;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Research results for methanol steam reforming and ethanol conversion in a conventional and a membrane reactor in the presence of Ru–Rh/DND, LiZr2(PO4)3, and Li1.1Zr1.9In0.1(PO4)3 catalysts have been described. The samples have been characterized by X-ray diffraction, scanning electron microscopy, and the BET method. The study of the catalytic properties of the catalyst composites has shown that the Ru–Rh/DND catalyst mostly mediates the dehydrogenation process, while LiZr2(PO4)3 and Li1.1Zr1.9In0.1(PO4)3 exhibit activity in both the dehydration and dehydrogenation reactions. The membrane process with a Pd–Ru alloy membrane provides a 20% increase in the hydrogen yield.
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页码：1048 / 1055
页数：7
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