Reversible addition-fragmentation chain-transfer polymerization: Fundamentals and use in practice

被引：0
|
作者：
E. V. Chernikova
E. V. Sivtsov
机构：
[1] Moscow State University,Faculty of Chemistry
[2] St. Petersburg State Technological Institute (Technical University),Institute of Macromolecular Compounds
[3] Russian Academy of Sciences,undefined
来源：
Polymer Science, Series B | 2017年 / 59卷
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摘要：
Modern approaches to the synthesis of tailor-made macromolecules by radical polymerization proceeding through the reversible addition-fragmentation chain-transfer mechanism are considered. The mechanism of this process and the experimental and calculation methods for determining its main kinetic parameters are discussed. Particular emphasis is placed on the problems of designing copolymers of various microstructures, including random, gradient, and block copolymers.
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页码：117 / 146
页数：29
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