The Interaction of 1H-Azoles With Nitrosochlorides of Adamantane Series

被引：0
|
作者：
P. E. Krasnikov
E. A. Sidnin
V. A. Osyanin
Yu. N. Klimochkin
机构：
[1] Samara State Technical University,
来源：
Chemistry of Heterocyclic Compounds | 2014年 / 50卷
关键词：
alkylidene adamantanes; α-azolyl oximes; 1; -azoles; nitrosoalkenes; nitrosochlorides; aza-Michael reaction;
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学科分类号：
摘要：
The interaction of nitrosochlorides based on 2-alkylidene adamantanes and 1Н-azoles in pyridine medium produced α-azolyl oximes of adamantane series. The reaction occurred as a conjugated 1,4-addition to in situ generated nitrosoalkenes acting as Michael acceptors. The structure of phenyl-[2-(4-phenyl-1Н-imidazol-1-yl)adamantan-2-yl]methanone (Е)-oxime was studied by X-ray crystallography.
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页码：1090 / 1101
页数：11
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