Lanthanide(III) Coordination Polymers with Longer-Spanning Flexible Ligand: Synthesis, Crystal Structure and Luminescence Property

被引:0
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作者
Yan Xie
Feng Ying Bai
Yong Heng Xing
Zhuo Wang
Zhi Feng Pu
Mao Fa Ge
机构
[1] Liaoning Normal University,College of Chemistry and Chemical Engineering
[2] Chinese Academy of Sciences,Institute of Chemistry
关键词
2D lanthanide coordination complex; Sebacic acid; Synthesis; Crystal structure;
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摘要
Two new two-dimensional (2D) lanthanide-organic frameworks [Ln (C10H16O4)1.5(H2O)2][Ln = Tb(1), Eu(2)] have been synthesized and characterized by elemental analyses, IR, XRD, and the X-ray diffraction. And the X-ray diffraction result shows that complex 1 is nine-coordinate and connected through the carboxylate groups of sebacate ligands to generate an extended 2D layer structure. Furthermore, the thermogravimetric analyses of complex 1 and the luminescent properties of all the complexes were carried out.
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页码:258 / 263
页数:5
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