Graphene oxide wrapped Cu-MOF as an efficient adsorbent for uranium extraction from aqueous solution

被引:0
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作者
Jinlu Chen
Xuan Yang
Lianyun Wang
Xiaoli Chen
Zui Tao
Songbo Tan
Fangzhu Xiao
Guowen Peng
机构
[1] University of South China,School of Chemistry and Chemical Engineering
[2] University of South China,School of Resources Environment and Safety Engineering
[3] University of South China,School of Public Health
[4] University of South China,Hunan Engineering Research Center for the Safety Control and Recycling of Radioactive Heavy Metal Pollutants
关键词
Cu-BTC; GO; Metal–organic frameworks (MOFs); Uranium adsorption;
D O I
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学科分类号
摘要
A hydrothermal and ethanol activation method is proposed to synthesize Cu-BTC and graphite oxide composites (Cu-BTC/GO). The uranium dynamic adsorption behavior was investigated by varying the addition of graphene oxide. The result showed that Langmuir isotherm and quasi-secondary kinetic model (R2 > 0.99) were more consistent with the adsorption process of uranium (VI) on this composite, and the maximum uranium adsorption was 150.50 mg g−1. The thermodynamic parameters indicated that this adsorption process was spontaneous and endothermic. After five adsorption–desorption cycles, the adsorption efficiency can still reach 76.6–78.9%. This study will help to draw a promising roadmap to describe the adsorption performance of Cu-BTC/GO composites for uranium.
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页码:263 / 279
页数:16
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