Exciton photoluminescence of ZnSe and CdS quantum dots in borosilicate glasses prepared by the sol-gel method

The spectra of exciton photoluminescence (PL) of ZnSe and CdS quantum dots (QDs) synthesized in borosilicate glasses by the sol-gel method are measured and analyzed. It is shown that the positions of the PL bands in the spectra of both systems are related to the spatial quantization of the energy of excitons in QDs. Significant differences in the conditions of this process in ZnSe and CdS QDs are revealed. It is ascertained that, at some critical concentration of the semiconductors (xcr), exciton percolation levels are formed in both systems, which manifest themselves in an abrupt change in the shape and spectral position of the emission bands of both systems and the constancy of the noted band parameters with a further increase in the concentration. The values of the critical and mean radii of QDs in the stage of their Ostwald ripening are obtained for several concentrations of the doping semiconductors.