Synthesis and Crystal Structure of [Li(THF)4]Cu2Br4

被引：0

作者：

Günter Margraf

Michael Bolte

Matthias Wagner

Hans-Wolfram Lerner

机构：

[1] Johann Wolfgang Goethe-Universität Frankfurt am Main,Institut für Anorganische Chemie

来源：

Journal of Chemical Crystallography | 2007年 / 37卷

关键词：

Coordination chemistry; Copper; Redox chemistry; X-ray structure analysis;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The mixed-valence compound [Li(THF)4]Cu2Br4 was synthesized in a redox reaction from 1,4-dihydroxynaphthalene, CuBr2 and LiNtBuSiMe3 in THF. X-ray quality crystals of [Li(THF)4]Cu2Br4 (monoclinic, P21/c) are obtained from the mother liquor at ambient temperature. In the solid state, infinite chains of anionic [Cu2Br4]− units are established. These chains are separated by [Li(THF)4]+ cations.

引用

页码：503 / 506

页数：3

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