Synthesis and Crystal Structure of [Li(THF)4]Cu2Br4

被引：0
|
作者：
Günter Margraf
Michael Bolte
Matthias Wagner
Hans-Wolfram Lerner
机构：
[1] Johann Wolfgang Goethe-Universität Frankfurt am Main,Institut für Anorganische Chemie
来源：
Journal of Chemical Crystallography | 2007年 / 37卷
关键词：
Coordination chemistry; Copper; Redox chemistry; X-ray structure analysis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The mixed-valence compound [Li(THF)4]Cu2Br4 was synthesized in a redox reaction from 1,4-dihydroxynaphthalene, CuBr2 and LiNtBuSiMe3 in THF. X-ray quality crystals of [Li(THF)4]Cu2Br4 (monoclinic, P21/c) are obtained from the mother liquor at ambient temperature. In the solid state, infinite chains of anionic [Cu2Br4]− units are established. These chains are separated by [Li(THF)4]+ cations.
引用
收藏
页码：503 / 506
页数：3
相关论文
共 50 条
  • [1] Synthesis and crystal structure of [Li(THF)4]Cu2Br4
    Margraf, Gunter
    Bolte, Michael
    Wagner, Matthias
    Lerner, Hans-Wolfram
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2007, 37 (07) : 503 - 506
  • [2] SYNTHESIS AND CRYSTAL STRUCTURE OF[Li.4THF][GdCl4·2THF]
    Ke WEN Zhong Sheng JIN Wen Qi CHEN Changchun Institute of Applied Chemistry
    Chinese Chemical Letters, 1991, (09) : 697 - 698
  • [3] Synthesis of homoleptic lanthanide amides and the crystal structure of [Li(THF)4][Y(NPh2)4]
    Yao, YM
    Lu, XH
    Shen, Q
    Yu, KB
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2004, 34 (04) : 275 - 279
  • [4] Synthesis of homoleptic lanthanide amides and the crystal structure of [Li(THF)4][Y(NPh2)4]
    Yingming Yao
    Xinhua Lu
    Qi Shen
    Kaibei Yu
    Journal of Chemical Crystallography, 2004, 34 : 275 - 279
  • [5] SYNTHESIS AND STRUCTURE OF A MOLYBDENUM GADOLINIUM HETEROMETALLIC COMPLEX - THE STRUCTURE OF [LI(THF)4]2[CP2MOSGDBR4(THF)]2
    MAGULL, J
    MANDEL, A
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (05): : 819 - 821
  • [6] SYNTHESIS AND CRYSTAL-STRUCTURE OF [LI(THF)4]2[BI4I14(THF)2], [LI(THF)4]4[BI5I19], AND (PH4P)4[BI6I22]
    KRAUTSCHEID, H
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (09): : 1559 - 1564
  • [7] Synthesis, Crystal Structure and Properties of Li2Cu5(PO4)4
    Snyder, K.
    Glaum, Robert
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2012, 638 (09): : 1287 - 1292
  • [8] A novel cage organotellurate(IV) macrocyclic host encapsulating a bromide anion guest:: [Li(THF)4][{(PriTe)12O16Br4{Li(THF)Br}4}Br]•2THF
    Citeau, H
    Kirschbaum, K
    Conrad, O
    Giolando, DM
    CHEMICAL COMMUNICATIONS, 2001, (19) : 2006 - 2007
  • [9] CRYSTAL-STRUCTURE OF BIS(TETRAETHYLAMMONIUM) DI-MU-BROMO-DIBROMODICUPRATE(I), [N(C2H5)4]2[CU2BR4]
    ASPLUND, M
    JAGNER, S
    ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1984, 38 (02): : 135 - 139
  • [10] SYNTHESIS AND CRYSTAL-STRUCTURE OF [LI(THF)4][((T)BUCP)YB(NPH2)3]
    MAO, LS
    SHEN, Q
    JIN, SC
    POLYHEDRON, 1994, 13 (6-7) : 1023 - 1025
12345