Synthesis and catalytic properties of M0.5(1 + x)FexTi2 − x(PO4)3 (M = Co, Ni, Cu; 0 ≤ x ≤ 2) for methanol conversion reactions

被引：0
|
作者：
E. A. Asabina
N. V. Orekhova
M. M. Ermilova
V. I. Pet’kov
I. O. Glukhova
N. A. Zhilyaeva
A. B. Yaroslavtsev
机构：
[1] Lobachevsky State University,Topchiev Institute of Petrochemical Synthesis
[2] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[3] Russian Academy of Sciences,undefined
来源：
Inorganic Materials | 2015年 / 51卷
关键词：
Methanol Conversion; Zirconium Phosphate; Methanol Dehydration; Nickel Phosphate; Mixed Phosphate;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
New phosphates with the general formula M0.5(1 + x)FexTi2 − x(PO4)3 (M = Co, Ni, Cu; 0 ≤ x ≤ 2) have been synthesized by a sol-gel process. We have studied phase relations in these systems and determined the composition stability limits of NASICON-type solid solutions. The catalytic properties of the phosphates for methanol dehydration and dehydrogenation reactions have been investigated in an inert atmosphere.
引用
收藏
页码：793 / 798
页数：5
相关论文
共 50 条
  • [21] Antimicrobial properties of co-doped tricalcium phosphates Ca3-2x(M′M′′)x(PO4)2 (M = Zn2+, Cu2+, Mn2+ and Sr2+)
    Deyneko, Dina V.
    Fadeeva, Inna V.
    Borovikova, Elena Yu
    Dzhevakov, Pavel B.
    Slukin, Pavel V.
    Zheng, Yufeng
    Xia, Dandan
    Lazoryak, Bogdan I.
    Rau, Julietta V.
    CERAMICS INTERNATIONAL, 2022, 48 (20) : 29770 - 29781
  • [22] Synthesis and characterization of the K(1-x)RbxCuFe(PO4)2 (0≤x≤1) phosphates
    Badri, Abdessalem
    Hidouri, Mourad
    Luisa Lopez, Maria
    Pico, Carlos
    Wattiaux, Alain
    Ben Amara, Mongi
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C397 - C397
  • [23] Phase Stability of Lead Phosphate Apatite Pb10-x Cu x (PO4)6O, Pb10-x Cu x (PO4)6(OH)2 (x=0, 1), and Pb8Cu2(PO4)6
    Shen, Jiahong
    Gaines, Dale
    Shahabfar, Shima
    Li, Zhi
    Kang, Dohun
    Griesemer, Sean
    Salgado-Casanova, Adolfo
    Liu, Tzu-chen
    Chou, Chang-Ti
    Xia, Yi
    Wolverton, Chris
    CHEMISTRY OF MATERIALS, 2023, 36 (01) : 275 - 285
  • [24] Phase stability and neutron diffraction studies of Laves phases Zr(Cr(1-x)M(x))(2) with M=(Cu0.5Ni0.5) and 0<x<0.2 and their hydrides
    Soubeyroux, JL
    Bououdina, M
    Fruchart, D
    deRango, P
    JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 231 (1-2) : 760 - 765
  • [25] Synthesis and X-ray characterization of Li(1-2x)NixTiO(PO4) (0≤x≤0.50)
    Manoun, B
    El Jazouli, A
    Gravereau, P
    Chaminade, JP
    POWDER DIFFRACTION, 2003, 18 (04) : 301 - 305
  • [26] Synthesis and Catalytic Performance of Na2HfM(PO4)3 and Ag2-xNaxHfM(PO4)3 (M = Fe and Al and 0.07 ≤ x ≤ 0.13)
    Palla, Suresh
    Veldurthi, Naveen Kumar
    Guje, Ravinder
    Prasad, G.
    Munirathnam, N. R.
    Vithal, M.
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2015, 45 (05) : 730 - 739
  • [27] Synthesis of X3(PO4)2 [X = Ni, Cu, Mn] Nanomaterials as an Efficient Electrode for Energy Storage Applications
    Saravanakumar, B.
    Haritha, A.
    Ravi, G.
    Yuvakkumar, R.
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2020, 20 (05) : 2813 - 2822
  • [28] X-RAY-DIFFRACTION STUDIES OF SOLID-SOLUTIONS OF M3(PO4)2 IN CO3(PO4)2
    NORD, AG
    ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1982, 36 (02): : 95 - 99
  • [29] Structure Formation and Thermal Expansion of M0.5+xMgxZr2–x(PO4)3 (M = Cd, Sr) Phosphates
    E. R. Perova
    P. A. Maiorov
    E. A. Asabina
    V. I. Pet’kov
    A. M. Kovalskii
    Inorganic Materials, 2021, 57 : 741 - 747
  • [30] Structure Formation and Thermal Expansion of M0.5+xMgxZr2-x(PO4)3 (M = Cd, Sr) Phosphates
    Perova, E. R.
    Maiorov, P. A.
    Asabina, E. A.
    Pet'kov, V., I
    Kovalskii, A. M.
    INORGANIC MATERIALS, 2021, 57 (07) : 741 - 747
12345