Synthesis and catalytic properties of M0.5(1 + x)FexTi2 − x(PO4)3 (M = Co, Ni, Cu; 0 ≤ x ≤ 2) for methanol conversion reactions

被引：0
|
作者：
E. A. Asabina
N. V. Orekhova
M. M. Ermilova
V. I. Pet’kov
I. O. Glukhova
N. A. Zhilyaeva
A. B. Yaroslavtsev
机构：
[1] Lobachevsky State University,Topchiev Institute of Petrochemical Synthesis
[2] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[3] Russian Academy of Sciences,undefined
来源：
Inorganic Materials | 2015年 / 51卷
关键词：
Methanol Conversion; Zirconium Phosphate; Methanol Dehydration; Nickel Phosphate; Mixed Phosphate;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
New phosphates with the general formula M0.5(1 + x)FexTi2 − x(PO4)3 (M = Co, Ni, Cu; 0 ≤ x ≤ 2) have been synthesized by a sol-gel process. We have studied phase relations in these systems and determined the composition stability limits of NASICON-type solid solutions. The catalytic properties of the phosphates for methanol dehydration and dehydrogenation reactions have been investigated in an inert atmosphere.
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页码：793 / 798
页数：5
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