121,123Sb NQR study of solid phases formed in systems (MF)1−x−(M′F)x−SbF3−H2O (M, M′=Na, K, Rb, Cs, and NH4)

被引：0
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作者：
L. A. Zemnukhova
R. L. Davidovich
G. A. Fedorishcheva
机构：
[1] Far-Eastern Branch of the Russian Academy of Sciences,Institute of Chemistry
来源：
Russian Chemical Bulletin | 1999年 / 48卷
关键词：
antimony(III), fluoride complexes, statistically disordered mixed crystals; Sb NQR spectra;
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摘要：
Crystalline substances formed in the (MF)1−x−(M′F)x−SbF3−H2O systems (M, M′=Na, K, Rb, Cs, and NH4;x=0 to 1) were investigated by121,123Sb NQR spectroscopy at 77 K. The formation of individual SbIII complexes NaCs3Sb4F16·H2O and NaKSbF5·1.5H2O, and statistically disordered mixed crystals M1−x−M′x−SbF4 (M, M′=K, Rb, Cs, and NH4) was established.
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页码：110 / 113
页数：3
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