121,123Sb NQR study of solid phases formed in systems (MF)1-x-(M′F)x-SbF3-H2O (M, M′ = Na, K, Rb, Cs, and NH4)

被引：7
|
作者：
Zemnukhova, LA [1 ]
Davidovich, RL [1 ]
Fedorishcheva, GA [1 ]
机构：
[1] Russian Acad Sci, Inst Chem, Far Eastern Branch, Vladivostok 690022, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 01期
关键词：
antimony(III); fluoride complexes; statistically disordered mixed crystals; Sb-121; Sb-123 NQR spectra;
D O I：
10.1007/BF02494410
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Crystalline substances formed in the (MF)(1-x)(M'F)(x)-SbF3-H2O systems (M, M' = Na, K, Rb, Cs, and NH4; x = 0 to 1) were investigated by Sb-121,Sb-123 NQR spectroscopy at 77 K. The formation of individual Sb-III complexes NaCs3Sb4F16 . H2O and NaKSbF5 . 1.5H(2)O, and statistically disordered mixed crystals M1-x-M'(x)-SbF4 (M, M' = K, Rb, Cs, and NH4) was established.
引用
收藏
页码：110 / 113
页数：4
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