Complexes of iron(III) salen and saloph Schiff bases with bridging 2,4,6-tris(2,5-dicarboxyphenylimino-4-formylphenoxy)-1,3,5-triazine and 2,4,6-tris(4-carboxyphenylimino-4′-formylphenoxy)-1,3,5-triazine

被引：0
|
作者：
Ziya Erdem Koc
H. Ismet Ucan
机构：
[1] Selcuk University,Department of Chemistry
来源：
Transition Metal Chemistry | 2007年 / 32卷
关键词：
Triazine; Salen; Transition Meet; AcOEt; Salicylidene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Four new trinuclear Fe(III) complexes involving tetradenta Schiff bases N,N1-bis(salicylidene) ethylenediamine-(salenH2) or bis(salicylidene)-o-phenylenediamine-(salophH2) with 2,4,6-tris(2,5-dicarboxyphenylimino-4-formylphenoxy)-1,3,5-triazine (DCPI-TRIPOD) or 2,4,6-tris(4-carboxyphenylimino-4′-formylphenoxy)-1,3,5-triazine (CPI-TRIPOD) have been synthesized and characterized by means of elemental analysis carrying out 1H-n.m.r., i.r. spectroscopy, thermal analyses and magnetic susceptibility measurements. The complexes can also be characterized as high-spin distorted octahedral FeIII bridged by carboxylic acids. The tricarboxylic acids play a role as bridges for weak antiferromagnetic intramolecular exchange.
引用
收藏
页码：597 / 602
页数：5
相关论文
共 50 条
  • [41] Theoretical Study of 2,4,6-Tris(3',5'-Diamino-2',4',6'-Trinitrophenylamino)-1,3,5-Triazine
    Ju, Xue-Hai
    Wang, Zun-Yao
    JOURNAL OF ENERGETIC MATERIALS, 2009, 27 (01) : 51 - 62
  • [42] Synthesis and Characterization of Tripodal Oxy-Schiff base (2,4,6-Tris(4-Carboxymethylenephenylimino-4′-formylphenoxy)-1,3,5-triazine) and the Thermal and Magnetic Properties of its Fe(III)/Cr(III) Complexes
    Koc, Ziya Erdem
    Uysal, Saban
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2011, 21 (03) : 400 - 406
  • [43] Synthesis and Characterization of Tripodal Oxy-Schiff base (2,4,6-Tris(4-Carboxymethylenephenylimino-4′-formylphenoxy)-1,3,5-triazine) and the Thermal and Magnetic Properties of its Fe(III)/Cr(III) Complexes
    Ziya Erdem Koç
    Şaban Uysal
    Journal of Inorganic and Organometallic Polymers and Materials, 2011, 21
  • [44] Trisubstituted 1,3,5-Triazines. 6. Synthesis of 2,4,6-Tris(acetonyl)-1,3,5-triazine
    A. V. Shastin
    T. I. Godovikova
    B. L. Korsunskii
    Chemistry of Heterocyclic Compounds, 2003, 39 (8) : 1037 - 1040
  • [45] Hydrolysis of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine with Pd(II) and Pt(II) Complexes
    Cruz-Estrada, Leonardo E.
    Hernandez-Ortega, Simon
    Valdes-Martinez, Jesus
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2023, 53 (01) : 127 - 137
  • [46] Hydrolysis of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine with Pd(II) and Pt(II) Complexes
    Leonardo E. Cruz-Estrada
    Simón Hernández-Ortega
    Jesús Valdés-Martínez
    Journal of Chemical Crystallography, 2023, 53 : 127 - 137
  • [47] Aquatriphenyl(trifluoroacetato)tin-2,4,6-tris(2-pyridyl)-1,3,5-triazine (1/1)
    Chee, CF
    Lo, KM
    Ng, SW
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 : M661 - M662
  • [48] Reaction of 2,4,6-triazido-1,3,5-triazine with triphenylphosphane.: Syntheses and characterization of the novel 2-triphenylphosphanimino-4-azidotetrazolo[5,1-a]-[1,3,5]triazine and 2,4,6-tris(triphenylphosphanimino)-1,3,5-triazine
    Kessenich, E
    Polborn, K
    Schulz, A
    INORGANIC CHEMISTRY, 2001, 40 (06) : 1102 - 1109
  • [49] 2,4,6-Tris[2-(diphenylphosphoryl)-4-ethylphenoxy]-1,3,5-triazine: A new ligand for lithium binding
    Ivanova, Irina S.
    Ilyukhin, Andrey B.
    Tsebrikova, Galina S.
    Polyakova, Irina N.
    Pyatova, Elena N.
    Solov'ev, Vitaly P.
    Baulin, Vladimir E.
    Tsivadze, Aslan Yu
    INORGANICA CHIMICA ACTA, 2019, 497
  • [50] RUTHENIUM CARBONYL-COMPLEXES OF 2,4,6-TRIS(2-PYRIDYL)-1,3,5-TRIAZINE - CRYSTAL-STRUCTURE OF METHOXIDE-SUBSTITUTED [MU-2,4,6-TRIS(2-PYRIDYL)-1,3,5-TRIAZINE]BIS[DICARBONYLDICHLORORUTHENIUM(II)]
    THOMAS, NC
    FOLEY, BL
    RHEINGOLD, AL
    INORGANIC CHEMISTRY, 1988, 27 (19) : 3426 - 3429
12345