Effect of temperature on thiocarbamide isomerization in concentrated aqueous solutions

被引：0
|
作者：
L. K. Altunina
V. A. Kuvshinov
N. I. Rodionova
T. V. Petrenko
V. D. Ogorodnikov
机构：
[1] Russian Academy of Sciences,Institute of Petroleum Chemistry, Siberian Branch
来源：
Russian Journal of Applied Chemistry | 2011年 / 84卷
关键词：
Produce Water; Petroleum Chemistry; Isomerization Reaction; Isomerization Ratio; Ammonium Thiocyanate;
D O I：
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中图分类号：
学科分类号：
摘要：
The reaction of isomerization of thiocarbamide to ammonium thiocyanate in aqueous concentrated solutions at temperatures from 100 to 150°C was studied by UV and NMR spectroscopy, as well as by photocolorimetric and conductometric methods. The isomerization reaction rate constants, activation energy, and isomerization ratio were calculated.
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页码：993 / 996
页数：3
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