Effect of the nature of a fluorinated substituent on the synthesis of functionalized 1,3-diketones

被引：0
|
作者：
Yu. S. Kudyakova
A. Ya. Onoprienko
Yu. O. Edilova
Ya. V. Burgart
V. I. Saloutin
D. N. Bazhin
机构：
[1] Ural Branch of the Russian Academy of Sciences,I. Ya. Postovsky Institute of Organic Synthesis
[2] Ural Federal University named after the first President of Russia B. N. Yeltsin,undefined
来源：
Russian Chemical Bulletin | 2021年 / 70卷
关键词：
fluorinated 1,3-diketones; Claisen condensation; acetals; transition metal diketonates;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The synthesis of alkali metal and copper(ii) 1-polyfluoroalkyl-4,4-dimethoxypentane-1,3-dionates is reported. The subsequent treatment of these compounds with oxalic acid or ethylenediaminetetraacetic acid disodium salt affords functionalized 1,3-diketones. The nature of the polyfluoroalkyl substituent was found to affect the conditions of the Claisen condensation and the stability of the acetal group in acidic medium.
引用
收藏
页码：745 / 752
页数：7
相关论文
共 50 条
  • [31] Biginelli condensations of fluorinated 3-oxo esters and 1,3-diketones [1]
    Saloutin, VI
    Burgart, YV
    Kuzueva, OG
    Kappe, CO
    Chupakhin, ON
    JOURNAL OF FLUORINE CHEMISTRY, 2000, 103 (01) : 17 - 23
  • [32] Recent Progress in the Synthesis of Heterocycles based on 1,3-Diketones
    Talbi, Soumaya
    Dib, Mustapha
    Bouissane, Latifa
    Abderrafia, Hafid
    Rabi, Souad
    Khouili, Mostafa
    CURRENT ORGANIC SYNTHESIS, 2022, 19 (02) : 220 - 245
  • [33] Synthesis of 3-phenoxyphenyl-containing 1,3-diketones
    Yu. V. Popov
    T. K. Korchagina
    V. S. Lobasenko
    S. A. Pavel’ev
    Russian Journal of General Chemistry, 2014, 84 : 2264 - 2266
  • [34] Synthesis of 3-phenoxyphenyl-containing 1,3-diketones
    Popov, Yu V.
    Korchagina, T. K.
    Lobasenko, V. S.
    Pavel'ev, S. A.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2014, 84 (11) : 2264 - 2266
  • [35] Preparation of cyclic 1,3-diketones and their exploitation in the synthesis of heterocycles
    Milan, M
    Viktor, M
    Rudolf, K
    Dusan, I
    CURRENT ORGANIC CHEMISTRY, 2004, 8 (08) : 695 - 714
  • [36] CLEMMENSEN REDUCTION OF 1,3-DIKETONES
    BAKER, KM
    DAVIS, BR
    CHEMISTRY & INDUSTRY, 1966, (19) : 768 - &
  • [37] Solid-phase synthesis of traceless 1,3-diketones
    Park, KH
    Cox, LJ
    TETRAHEDRON LETTERS, 2003, 44 (05) : 1067 - 1069
  • [38] The regioselective preparation of 1,3-diketones
    Wiles, C
    Watts, P
    Haswell, SJ
    Pombo-Villar, E
    TETRAHEDRON LETTERS, 2002, 43 (16) : 2945 - 2948
  • [39] ALKYLATION OF CYCLIC 1,3-DIKETONES
    RAJAMANNAR, T
    PALANI, N
    BALASUBRAMANIAN, KK
    SYNTHETIC COMMUNICATIONS, 1993, 23 (22) : 3095 - 3108
  • [40] CLEMMENSEN REDUCTION OF 1,3-DIKETONES
    CUSACK, NJ
    DAVIS, BR
    JOURNAL OF ORGANIC CHEMISTRY, 1965, 30 (06): : 2062 - &
12345