Investigation of photocatalytic performances of sulfur based reduced graphene oxide-TiO2 nanohybrids

被引:26
|
作者
Raghavan, Nivea [1 ]
Thangavel, Sakthivel [1 ]
Sivalingam, Yuvaraj [2 ]
Venugopal, Gunasekaran [3 ]
机构
[1] Karunya Inst Technol & Sci, Sch Engn & Technol, Dept Sci & Technol, Coimbatore 641114, Tamil Nadu, India
[2] SRM Inst Sci & Technol, Dept Phys & Nanotechnol, SRM Res Inst, Kattangulathur Campus, Madras, Tamil Nadu, India
[3] Cent Univ Tamil Nadu, Sch Technol, Dept Mat Sci, Thiruvarur 610005, Tamil Nadu, India
关键词
Graphene oxide; Sulfur; Photo catalyst; TiO2; S-DOPED TIO2; VISIBLE-LIGHT; HYDROGEN-PRODUCTION; WATER; NANOPARTICLES; BATTERIES; POWDERS; TIS2;
D O I
10.1016/j.apsusc.2018.01.043
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hypothesized the incorporation of direct elemental sulfur (S) into graphene-oxide (GO) via simple sonication. Initially S@GO was prepared using simple ultrasonication and evaluated its photocatalytic property. In S@GO instead of photocatalytic activity the adsorption was predominant due the amphiphilic property of GO. Later, S@GO was utilized to prepare sulfur based rGO-TiO2 [S@rGO-TiO2 or SRT] hybrids using solvothermal method. Herein the addition of ubiquitous sulfur has been hypothesized to improve the efficiency of photocatalyst. When S@GO subjected to solvothermal treatment, unpredicted reaction took place and it is discussed later briefly, yet this S@rGO-TiO2 hybrid demonstrated high photocatalytic activity. Some essential characterization such as SEM, EDAX, XRD and Raman analysis were carried out and its photocatalytic performance were evaluated and compared with TiO2 and reduced graphene-oxide-TiO2. Our investigations will create a new pathway in futuristic development of SRT hybrids suitable for photocatalytic and waste-water treatment/remedial applications. (C) 2018 Elsevier B.V. All rights reserved.
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页码:712 / 718
页数:7
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