Transesterification of Cyclic Carbonates to Dimethyl Carbonate Using Solid Oxide Catalyst at Ambient Conditions: Environmentally Benign Synthesis

被引：35

作者：

Sankar, Meenakshisundaram ^{[1
,4
]}

Satav, Srikanth ^{[2
,4
]}

Manikandan, Palanichamy ^{[3
,4
]}

机构：

[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales

[2] ETH Honggerberg, Dept Chem & Bioengn, CH-8093 Zurich, Switzerland

[3] Dow Chem Int Pvt Ltd, Pune, Maharashtra, India

[4] Natl Chem Lab, Catalysis & Inorgan Chem Div, Pune 411008, Maharashtra, India

来源：

CHEMSUSCHEM | 2010年 / 3卷 / 05期

关键词：

calcium; environmental chemistry; heterogeneous catalysis; transesterification zinc; ETHYLENE CARBONATE; METHANOL; DIOXIDE; EPOXIDES; CO2;

D O I：

10.1002/cssc.201000038

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Continuous synthesis at ambient conditions: Dimethyl carbonate (DMC) is an important methylating and carbonylating agent. Transesterification of cyclic carbonates using methanol for the synthesis of DMC is environmentally benign. CaO-ZnO catalysts, prepared by a wet impregnation method, are effective catalysts for the transesterification of ethylene carbonate using methanol in batch and in continuous reactors. Yields of ca. 84?% DMC can be achieved at ambient conditions. © 2010 Wiley-VCH Verlag GmbH& Co. KGaA, Weinheim.

引用

页码：575 / 578

页数：4

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