Application of Polyoxometalate in Synthesis of 2,5-Diformylfuran and Its Derivatives

被引:1
|
作者
Li, Zheng [1 ]
机构
[1] Beijing Inst Technol, Beijing 102488, Peoples R China
关键词
ONE-POT SYNTHESIS; SELECTIVE OXIDATION; FRUCTOSE; ACID;
D O I
10.1088/1755-1315/571/1/012150
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Because of the inherent defects of fossil resources, replacing fossil resources with biomass resources is a great challenge in the 21st century. 2,5-Diformyl furan (DFF) and its derivatives are important value-added chemicals derived from biomass platform chemicals 5-hydroxymethylfurfural (HMF) and fructose, which have great application in the field of medicine, biopolymer and scientific research. It is of great significance to select suitable catalyst to complete the conversion. Polyoxometalate is anionic metal oxide clusters, due to their excellent thermal stability and redox ability, polyoxometalate are widely used in catalytic oxidation and have been gradually used in biomass value-added conversion. The preparation of DFF and its derivatives from HMF and fructose using polyoxometalate has become a research hotspot in recent years.
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页数:5
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