Schiff base polymers derived from 2,5-diformylfuran

被引：73

作者：

Xiang, Tengfei ^{[1
]}

Liu, Xiumin ^{[1
]}

Yi, Ping ^{[2
]}

Guo, Mingming ^{[3
]}

Chen, Yusheng ^{[1
]}

Wesdemiotis, Chrys ^{[1
]}

Xu, Jie ^{[4
]}

Pang, Yi ^{[1
]}

机构：

[1] Univ Akron, Dept Chem, Akron, OH 44325 USA

[2] Univ Akron, Dept Civil Engn, Akron, OH 44325 USA

[3] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA

[4] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China

来源：

POLYMER INTERNATIONAL | 2013年 / 62卷 / 10期

关键词：

Schiff base; condensation polymerization; mass spectroscopy; NMR; OXIDATION; COMPLEXES;

D O I：

10.1002/pi.4452

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polymerization of 2,5-diformylfuran with two primary amines was carried out in acetonitrile and ethanol at room temperature. The reaction was characterized using a combination of mass spectroscopy and NMR spectroscopy, which revealed the clean formation of the imine -CH N-functional group. Although some cyclic products were detected from mass spectroscopy, the ring size was limited to products that have the -CH N-group only in anti-geometry. The furan Schiff bases exhibit good thermal stability. While mass spectra evidenced oligomers of different lengths, cross-polarization magic angle spinning 13C NMR spectra of the insoluble polymer revealed the linear structure as proposed. (C) 2013 Society of Chemical Industry

引用

页码：1517 / 1523

页数：7

共 50 条

[1] Sustainable Catalytic Synthesis of 2,5-Diformylfuran from Various Carbohydrates
Kim, Si Ae
Sung, Kihyuk
Jang, June Young
Bang, Sohee
Son, Seung Uk
Jang, Hye-Young
CATALYSTS, 2022, 12 (04)
[2] The mononuclear barium and dinuclear copper(II) complexes of a 24-membered bibracchial tetraimine Schiff base macrocycle derived from tris(2-aminoethyl)amine and 2,5-diformylfuran
Adams, H
Bailey, NA
Collinson, SR
Fenton, DE
Harding, CJ
Kitchen, SJ
INORGANICA CHIMICA ACTA, 1996, 246 (1-2) : 81 - 88
[3] The mononuclear barium and dinuclear copper(II) complexes of a 24-membered bibracchial tetraimine Schiff base macrocycle derived from tris(2-aminoethyl)amine and 2,5-diformylfuran
Inorg Chim Acta, 1-2 (81):
[4] Metal Free Acid Base Catalyst in the Selective Synthesis of 2,5-Diformylfuran from Hydroxynnethylfurfural, Fructose, and Glucose
Rathod, Pramod V.
Nale, Sagar D.
Jadhav, Vrushali H.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2017, 5 (01): : 701 - 707
[5] Synthesis of 2,5-diformylfuran from renewable carbohydrates and its applications: A review
Dai, Jinhang
GREEN ENERGY & ENVIRONMENT, 2021, 6 (01) : 22 - 32
[6] Application of Polyoxometalate in Synthesis of 2,5-Diformylfuran and Its Derivatives
Li, Zheng
2020 5TH INTERNATIONAL CONFERENCE ON MATERIALS SCIENCE, ENERGY TECHNOLOGY AND ENVIRONMENTAL ENGINEERING, 2020, 571
[7] Efficient Synthesis of 2,5-Dicyanofuran from Biomass-Derived 2,5-Diformylfuran via an Oximation-Dehydration Strategy
Xu, Yongming
Jia, Xiuquan
Ma, Jiping
Gao, Jin
Xia, Fei
Li, Xiaofang
Xu, Jie
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (03): : 2888 - 2892
[8] Synthesis of 2,5-diformylfuran from renewable carbohydrates and its applications: A review
Jinhang Dai
GreenEnergy&Environment, 2021, 6 (01) : 22 - 32
[9] Novel and Efficient Biotechnological Approach to Produce 2,5-Diformylfuran from Biomass-Derived 5-Hydroxymethylfurfural
Millan Acosta, Alberto
Cuesta Turull, Clara
Cosovanu, Diana
Sala Marti, Nuria
Canela-Garayoa, Ramon
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2021, 9 (43) : 14550 - 14558
[10] Recent Approaches in the Catalytic Transformation of Biomass-Derived 5-Hydroxymethylfurfural into 2,5-Diformylfuran
Phuong Hoang Tran
CHEMSUSCHEM, 2022, 15 (13)

← 1 2 3 4 5 →