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Bis(NHC)-Palladium(II) Complex-Catalyzed Dioxygenation of Alkenes

被引：87
|
作者：
Wang, Wenfeng [1 ,2 ]
Wang, Feijun [1 ,2 ]
Shi, Min [1 ,2 ,3 ]
机构：
[1] E China Univ Sci & Technol, Sch Chem & Mol Engn, Adv Mat Lab, Shanghai 200237, Peoples R China
[2] E China Univ Sci & Technol, Sch Chem & Mol Engn, Inst Fine Chem, Shanghai 200237, Peoples R China
[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ORGANOMETALLICS | 2010年 / 29卷 / 04期
基金：
中国国家自然科学基金;
关键词：
N-HETEROCYCLIC CARBENES; CROSS-COUPLING REACTIONS; FORMING REDUCTIVE ELIMINATION; C-H BONDS; PALLADIUM(IV) COMPLEXES; OXIDATIVE CYCLIZATION; MOLECULAR-OXYGEN; O BOND; ASYMMETRIC DIHYDROXYLATION; ELECTROPHILIC DIAMINATION;
D O I：
10.1021/om900975a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Bis(NHC)-Pd(II) complexes derived from 1,1'-binaphthyl-2,2'-diamine (BINAM) were successfully first used to catalyze the dioxygenation of alkenes under mild conditions tolerant of air and moisture. Cationic NHC-Pd2+ diaquo complex le showed the highest catalytic activity to give 1,2-dioxygenation products with good syn-diastercoselectivity for 1,2-disubstituted alkenes.
引用
收藏
页码：928 / 933
页数：6
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