Synthesis and Crystal Structure of 1-(2-Fluorophenyl)-3-(1H-1,2,4-triazol-1-yl)propan-1-one

被引：0
|
作者：
Zeng, Wulan [1 ]
Wang, Lintong [1 ]
Guo, Huanmei [1 ]
Jian, Fangfang [1 ]
机构：
[1] Weifang Univ, MicroScale Sci Inst, Dept Chem & Chem Engn, Weifang 261061, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2010年 / 22卷 / 08期
关键词：
Synthesis; Crystal structure; 1-(2-Fluorophenyl)-3-(1H-1,2,4-triazol-1-yl)propan-1-one; BIOLOGICAL-ACTIVITIES;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The compound 1-(2-fluorophenyl)-3-(1H-1,2,4-triazol-1-yl)propan-1-one, was synthesized and characterized by means of elemental analysis, IR spectrum and X-ray diffraction. It crystallizes in monoclinic, space group P2(1)/c with a = 11.757(15), b = 4.904(6), c = 21.50(3) angstrom, beta = 118.11(6)degrees, C(11)H(10)N(3)OF, M(r) = 219.21, V = 1093(2)angstrom(3), Z = 4, Dc = 1.326 g/cm(3), F(000) = 452, mu = 0.101 mm(-1), final R(1) = 0.1101. The triazole ring and 2-fluorophenyl ring makes dihedral angles of 85.97 degrees. There is obvious potentially weak intra- and intermolecular C-H center dot center dot center dot O hydrogen bonds in the crystal, which stabilizes the crystal structure.
引用
收藏
页码：6185 / 6189
页数：5
相关论文
共 50 条
  • [1] 1-(3-Nitrophenyl)-3-(1H-1,2,4-triazol-1-yl)propan-1-one
    Wan, J
    Li, CL
    Li, XM
    Li, Y
    Zhang, SS
    Xu, H
    Ouyang, PK
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O1997 - O1998
  • [2] 1-(4-Nitrophenyl)-3-(1H-1,2,4-triazol-1-yl)-propan-1-one
    Wan, J
    Li, CL
    Li, XM
    Zhang, SS
    Ouyang, PK
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O3394 - O3395
  • [3] 1-(4-methoxyphenyl)-3-(1H-1,2,4-triazol-1-yl)-propan-1-one
    Wan, J
    Li, CL
    Li, XM
    Zhang, SS
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O307 - O308
  • [4] 1-(4-hydroxyphenyl)-3-(1H-1,2,4-triazol-1-yl)-propan-1-one
    Liu, FQ
    Li, WH
    Song, HB
    Lu, LD
    Yang, XJ
    Wang, X
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O400 - O401
  • [5] 1-(2,4-difluorophenyl)-3-(1H-1,2,4-triazol-1-yl)propan-1-one
    Wang, Chen-Yi
    Guo, Ling-Xiang
    Chen, Jian-Zhong
    Xia, Ping
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O4331 - O4332
  • [6] 1-(4-Methylphenyl)-3-(1H-1,2,4-triazol-1-yl)-propan-1-one
    Wan, J
    Li, CL
    Li, XM
    Wang, SY
    Zhang, SS
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O2391 - O2392
  • [7] 1-(4-Methoxyphenyl)-3-(1H-1,2,4-triazol-1-yl)propan-1-one
    Wang, Wei
    Luo, Hao
    Li, Fang
    Bi, Sai
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O4639 - U4406
  • [8] 1-(4-chlorophenyl)-3-(1H-1,2,4-triazol-1-yl)-propan-1-one
    Xu, LZ
    Song, HB
    Liu, JH
    Li, K
    Shi, GD
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : O2404 - O2405
  • [9] 3-(1H-benzotriazol-1-yl)-1-(2-fluorophenyl)propan-1-one
    Zeng, Wu-Lan
    Bi, Sai
    Zhang, Fan
    Wan, Jun
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O5453 - O5454
  • [10] 1-Phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one hemihydrate
    Wan, J
    Li, CL
    Li, XM
    Zhang, SS
    Xu, H
    Ouyang, PK
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O1641 - O1642
12345