Synthesis, Characterization and Catalytic Application of Starch Supported Cuprous Iodide Nanoparticles

被引:10
|
作者
Mallick, Sadhucharan [1 ]
Mukhi, Priyabrata [2 ]
Kumari, Poonam [3 ]
Mahato, Kumari Reshmi [3 ]
Verma, Suryadev Kumar [3 ]
Das, Debjit [4 ]
机构
[1] Indira Gandhi Natl Tribal Univ, Dept Chem, Amarkantak, India
[2] Indian Inst Technol, Sch Basic Sci, Bhubaneswar, India
[3] Cent Univ Jharkhand, Ctr Appl Chem, Ranchi, Bihar, India
[4] Triveni Devi Bhalotia Coll, Dept Chem, Raniganj, India
关键词
Nanocatalysis; CuI NPs; Allylation; Indole; Allylic alcohol; ONE-POT SYNTHESIS; BOND FORMATION; NUCLEOPHILIC-SUBSTITUTION; EFFICIENT SYNTHESIS; ACTIVE METHYLENES; ALLYLIC ALCOHOLS; SN CATALYST; INDOLES; SUZUKI; GREEN;
D O I
10.1007/s10562-019-02909-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The starch supported cuprous iodide nanoparticles (CuI-NPs@Starch) were synthesized in aqueous medium and characterized by transmission electron microscopy, scanning electron microscopy, X-ray powder diffraction, energy-dispersive X-ray spectroscopy and atomic absorption spectra analysis. The newly synthesized CuI NPs on starch have been demonstrated first time as an efficient catalyst for the regioselective 3-allylation reaction of N-substituted indoles as well as ring-substituted indoles using various allyl alcohols under moisture and air insensitive conditions.
引用
收藏
页码:3501 / 3507
页数:7
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