Indium-Catalyzed N-Formylation of Amines under Solvent-Free Conditions

被引：55
|
作者：
Kim, Joong-Gon [2 ]
Jang, Doo Ok [1 ]
机构：
[1] Yonsei Univ, Dept Chem, Wonju 220710, South Korea
[2] Hanwha Chem R&D Ctr, Div Biotechnol, Taejon 305345, South Korea
来源：
SYNLETT | 2010年 / 08期
关键词：
amine; formylation; formic acid; indium; ethanolamine; formylamino ester; solvent-free; ACID-ESTERS; AQUEOUS-MEDIA; ORGANIC-REACTIONS; PEPTIDE-SYNTHESIS; CONVENIENT METHOD; MILD CONDITIONS; FACILE METHOD; ALCOHOLS; ANILINES; FORMATE;
D O I：
10.1055/s-0029-1219784
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We have developed a simple, mild method for N-formylation of a wide variety of amines in the presence of indium metal as a catalyst under solvent-free conditions. This reaction is applicable to the chemoselective N-formylation of amino groups and alpha-amino acid esters without epimerization.
引用
收藏
页码：1231 / 1234
页数：4
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