An Efficient Method for N-Formylation of Amines Using Natural HEU Zeolite at Room Temperature Under Solvent-Free Conditions

被引：27

作者：

Bahari, Siavash ^{[1
]}

Mohammadi-Aghdam, Babak ^{[1
]}

Sajadi, S. Mohammad ^{[2
]}

Zeidali, Fereshteh ^{[3
]}

机构：

[1] Islamic Azad Univ, Ahar Branch, Dept Chem, Ahar, Iran

[2] Univ Soran, Fac Sci, Dept Petr Geosci, Soran, Kurdistan Regio, Iraq

[3] Ilam Petrochem Complex, Ilam, Iran

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2012年 / 33卷 / 07期

关键词：

N-Formylation; Amines; Solvent-free; Natural HEU zeolite; Formic acid; SECONDARY-AMINES; HETEROGENEOUS CATALYST; REUSABLE CATALYST; FACILE METHOD; FORMIC-ACID; LEWIS-ACID; SILICA; FECL3-SIO2; REAGENT; ESTERS;

D O I：

10.5012/bkcs.2012.33.7.2251

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rapid and practical green route for N-formylation of primary and secondary amines with formic acid at room temperature under the solvent-free conditions using HEU zeolite as a heterogeneous, reusable and highly efficient catalyst is described. The process is remarkably simple and environmentally benign. Excellent chemoselectivity was observed for the conversion of primary amines in the presence of secondary amines.

引用

页码：2251 / 2254

页数：4

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