Autocatalytic character of anodic polymerization of aniline in water-organic acid solutions

被引：10
|
作者：
Ovsyannikova, EV [1 ]
Grosheva, MY [1 ]
Alpatova, NM [1 ]
机构：
[1] Russian Acad Sci, AN Frumkin Electrochem Inst, Moscow 119071, Russia
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2004年 / 40卷 / 10期
基金：
俄罗斯基础研究基金会;
关键词：
polyaniline; electrochemical synthesis; autocatalysis;
D O I：
10.1023/B:RUEL.0000046496.16092.15
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
A cyclic voltammetry study shows the anodic polymerization of aniline in 2 M HClO4 water-acetonitrile solutions to proceed via an EC: EC mechanism. In the chemical reaction, pernigraniline catalyzes the aniline oxidation, recovering from emeraldin in the second stage of the electrochemical process.
引用
收藏
页码：1089 / 1091
页数：3
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