A tuning of the spin crossover in Fe(II) complexes

被引：0
|
作者：
Boca, R [1 ]
机构：
[1] Slovak Univ Technol Bratislava, Dept Inorgan Chem, SK-81237 Bratislava, Slovakia
来源：
SOLID STATE CHEMISTRY V | 2003年 / 90-91卷
关键词：
spin crossover; Fe(II) complexes; transition enthalpy; transition entropy; transition temperature; cooperativeness;
D O I：
暂无
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Thermodynamic data for a series of Fe(11) spin crossover systems are analysed with the aim of tuning the transition temperature and the solid-state cooperativeness. The rigid tridentate ligands clearly shift the transition temperature close to room one as opposed to the capabilities of the bidentate counterparts. The enthalpy disfavour is responsible for it.
引用
收藏
页码：141 / 146
页数：6
相关论文
共 50 条
  • [31] Spin Crossover in Fe(II) Complexes with N4S2 Coordination
    Arroyave, Alejandra
    Lennartson, Anders
    Dragulescu-Andrasi, Alina
    Pedersen, Kasper S.
    Piligkos, Stergios
    Stoian, Sebastian A.
    Greer, Samuel M.
    Pak, Chongin
    Hietsoi, Oleksandr
    Hoa Phan
    Hill, Stephen
    McKenzie, Christine J.
    Shatruk, Michael
    [J]. INORGANIC CHEMISTRY, 2016, 55 (12) : 5904 - 5913
  • [32] CASPT2 molecular geometries of Fe(ii) spin-crossover complexes
    Finney, Brian A.
    Chowdhury, Sabyasachi Roy
    Kirkvold, Clara
    Vlaisavljevich, Bess
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2022, 24 (03) : 1390 - 1398
  • [33] DFT calculations as a tool to analyse quadrupole splittings of spin crossover Fe(II) complexes
    J. A. Wolny
    H. Paulsen
    H. Winkler
    A. X. Trautwein
    J.-P. Tuchagues
    [J]. Hyperfine Interactions, 2005, 166 : 495 - 498
  • [34] Varied spin crossover behaviour in a family of dinuclear Fe(II) triple helicate complexes
    Archer, Rosanna J.
    Scott, Hayley S.
    Polson, Matthew I. J.
    Williamson, Bryce E.
    Mathoniere, Corine
    Rouzieres, Mathieu
    Clerac, Rodolphe
    Kruger, Paul E.
    [J]. DALTON TRANSACTIONS, 2018, 47 (24) : 7965 - 7974
  • [35] DFT calculations as a tool to analyse quadrupole splittings of spin crossover Fe(II) complexes
    Wolny, J. A.
    Paulsen, H.
    Winkler, H.
    Trautwein, A. X.
    Tuchagues, J. -P.
    [J]. HYPERFINE INTERACTIONS, 2005, 166 (1-4): : 495 - 498
  • [36] CASPT2 geometries and energies of Fe(II) spin-crossover complexes
    Finney, Brian
    Vlaisavljevich, Bess
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
  • [37] Processable magnetic plastics composites - spin crossover of PMMA/Fe(II)-complexes composites
    Lee, SW
    Lee, JW
    Jeong, SH
    Park, IW
    Kim, YM
    Jin, JI
    [J]. SYNTHETIC METALS, 2004, 142 (1-3) : 243 - 249
  • [38] Fine-tuning of the spin-crossover properties of Fe(iii) complexes via ligand design
    Vidal, Daniel
    Cirera, Jordi
    Ribas-Arino, Jordi
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2023, 25 (17) : 12490 - 12499
  • [39] Spin Crossover in Fe(II) and Co(II) Complexes with the Same Click-Derived Tripodal Ligand
    Schweinfurth, David
    Demeshko, Serhiy
    Hohloch, Stephan
    Steinmetz, Marc
    Brandenburg, Jan Gerit
    Dechert, Sebastian
    Meyer, Franc
    Grimme, Stefan
    Sarkar, Biprajit
    [J]. INORGANIC CHEMISTRY, 2014, 53 (16) : 8203 - 8212
  • [40] Anionic Tuning of Spin Crossover in FeIII-Quinolylsalicylaldiminate Complexes
    Sertphon, Darunee
    Harding, David J.
    Harding, Phimphaka
    Murray, Keith S.
    Moubaraki, Boujemaa
    Cashion, John D.
    Adams, Harry
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, (5-6) : 788 - 795
12345