A tuning of the spin crossover in Fe(II) complexes

被引：0
|
作者：
Boca, R [1 ]
机构：
[1] Slovak Univ Technol Bratislava, Dept Inorgan Chem, SK-81237 Bratislava, Slovakia
来源：
SOLID STATE CHEMISTRY V | 2003年 / 90-91卷
关键词：
spin crossover; Fe(II) complexes; transition enthalpy; transition entropy; transition temperature; cooperativeness;
D O I：
暂无
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Thermodynamic data for a series of Fe(11) spin crossover systems are analysed with the aim of tuning the transition temperature and the solid-state cooperativeness. The rigid tridentate ligands clearly shift the transition temperature close to room one as opposed to the capabilities of the bidentate counterparts. The enthalpy disfavour is responsible for it.
引用
收藏
页码：141 / 146
页数：6
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