Fabrication and Characterization of Dye-Sensitized Solar Cells for Greenhouse Application

被引：23

作者：

Kim, Jeum-Jong ^{[1
]}

Kang, Mangu ^{[1
]}

Kwak, Ock Keum ^{[2
]}

Yoon, Yong-Jin ^{[3
,4
]}

Min, Kil Sik ^{[5
]}

Chu, Moo-Jung ^{[1
]}

机构：

[1] Elect & Telecommun Res Inst, IT Mat & Components Lab, Taejon 305700, South Korea

[2] Sun Moon Univ, Asan 336708, Chungnam, South Korea

[3] Gyeongsang Natl Univ, Grad Sch Mol Mat & Nanochem, Dept Chem, Jinju 660701, South Korea

[4] Gyeongsang Natl Univ, Grad Sch Mol Mat & Nanochem, Res Inst Nat Sci, Jinju 660701, South Korea

[5] Kyungpook Natl Univ, Dept Chem Educ, Taegu 702701, South Korea

来源：

INTERNATIONAL JOURNAL OF PHOTOENERGY | 2014年 / 2014卷

关键词：

CHARGE-TRANSFER; HIGH-EFFICIENCY; LIGHT; FILMS;

D O I：

10.1155/2014/376315

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have developed dye-sensitized solar cells using novel sensitizers with enhanced transmittance of red (625-675 nm) and blue (425-475 nm) wavebands to control the illumination condition in the greenhouse. Novel ruthenium bipyridyl sensitizers with general formulas (Me3PhN)(4)[Ru(dcbpy)(2)(NCS)(2)] (JJ-7) and (Me3BnN)(4)[Ru(dcbpy)(2)(NCS)(2)] (JJ-9) have been synthesized and demonstrated as efficient sensitizers in dye-sensitized solar cells for greenhouse application. Under standard AM 1.5 sunlight, the solar cell of JJ-7 using a liquid-based electrolyte exhibits a short-circuit photocurrent density of 8.49 mA/cm(2), an open-circuit voltage of 0.83 V, and a fill factor of 0.71, corresponding to an overall conversion efficiency of 4.96% on 5 mu m TiO2 film. The transmittance of JJ-7 and JJ-9 shows 62.0% and 61.0% at 660 nm and 18.0% and 15.0% at 440 nm for cultivation on 5 mu m TiO2 film, respectively.

引用

页数：7

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