Preparation and enantiomer recognition behaviour of azophenolic crown ethers containing cis-1-phenylcyclohexane-1,2-diol as the chiral subunit and 2,4-dinitrophenylazophenol as the chromophore

被引：22
|
作者：
Naemura, K [1 ]
Ueno, K [1 ]
Takeuchi, S [1 ]
Hirose, K [1 ]
Tobe, Y [1 ]
Kaneda, T [1 ]
Sakata, Y [1 ]
机构：
[1] OSAKA UNIV,INST SCI & IND RES,IBARAKI,OSAKA 567,JAPAN
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 04期
关键词：
D O I：
10.1039/p19960000383
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Optically active azophenolic crown ethers 1 and 2 incorporating two cis-1-phenylcyclohexane-1,2-diol chiral subunits and a p-(2,4-dinitrophenylazo)phenol moiety as a chromophore have been prepared and the enantiomer recognitive coloration in complexation with chiral ethylamine and 2-aminoethanol derivatives has been examined, The observed enantiomer selectivities of crown ethers 1 and 2 have been interpreted on the basis of CPK molecular model examination of the diastereoisomeric complexes.
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页码：383 / 388
页数：6
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