Dihydrolevoglucosenone (Cyrene) as a bio-based alternative for dipolar aprotic solvents

被引：337

作者：

Sherwood, James ^{[1
]}

De Bruyn, Mario ^{[1
]}

Constantinou, Andri ^{[1
]}

Moity, Laurianne ^{[1
]}

McElroy, C. Rob ^{[1
]}

Farmer, Thomas J. ^{[1
]}

Duncan, Tony ^{[2
]}

Raverty, Warwick ^{[2
]}

Hunt, Andrew J. ^{[1
]}

Clark, James H. ^{[1
]}

机构：

[1] Univ York, Green Chem Ctr Excellence, Dept Chem, York YO10 5DD, N Yorkshire, England

[2] Circa Grp Pty Ltd, Knoxfield, Vic 3180, Australia

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 68期

关键词：

SOLVATOCHROMIC PARAMETERS; HYDROGEN GENERATION; GREEN CHEMISTRY; CATALYSIS; BETA;

D O I：

10.1039/c4cc04133j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dihydrolevoglucosenone (Cyrene) is a bio-based molecule, derived in two simple steps from cellulose, which demonstrates significant promise as a dipolar aprotic solvent. The dipolarity of dihydrolevoglucosenone is similar to NMP, DMF and sulpholane. Dihydrolevoglucosenone demonstrates similar performance to NMP in a fluorination reaction and the Menschutkin reaction.

引用

页码：9650 / 9652

页数：3

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