Dihydrolevoglucosenone (Cyrene) as a bio-based alternative for dipolar aprotic solvents

被引：337
|
作者：
Sherwood, James [1 ]
De Bruyn, Mario [1 ]
Constantinou, Andri [1 ]
Moity, Laurianne [1 ]
McElroy, C. Rob [1 ]
Farmer, Thomas J. [1 ]
Duncan, Tony [2 ]
Raverty, Warwick [2 ]
Hunt, Andrew J. [1 ]
Clark, James H. [1 ]
机构：
[1] Univ York, Green Chem Ctr Excellence, Dept Chem, York YO10 5DD, N Yorkshire, England
[2] Circa Grp Pty Ltd, Knoxfield, Vic 3180, Australia
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 68期
关键词：
SOLVATOCHROMIC PARAMETERS; HYDROGEN GENERATION; GREEN CHEMISTRY; CATALYSIS; BETA;
D O I：
10.1039/c4cc04133j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dihydrolevoglucosenone (Cyrene) is a bio-based molecule, derived in two simple steps from cellulose, which demonstrates significant promise as a dipolar aprotic solvent. The dipolarity of dihydrolevoglucosenone is similar to NMP, DMF and sulpholane. Dihydrolevoglucosenone demonstrates similar performance to NMP in a fluorination reaction and the Menschutkin reaction.
引用
收藏
页码：9650 / 9652
页数：3
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