Proton-coupled electron transfer from sulfur:: A S-H/S-D kinetic isotope effect of ≥ 31.1

被引：0

作者：

Huynh, MHV ^{[1
]}

White, PS ^{[1
]}

Meyer, TJ ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Venable & Kenan Labs, Chapel Hill, NC 27599 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2000年 / 39卷 / 22期

关键词：

isotope effects; kinetics; osmium; reductions; S ligands;

D O I：

10.1002/1521-3773(20001117)39:22<4101::AID-ANIE4101>3.0.CO;2-E

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Not bound to a metal and yet still involved in proton-coupled electron transfer - this is the distinguishing property of the sulfur center of the complex [Os(IV)(tpy)(Cl)2{NS(H)C6H3Me2}]+ (1, tpy = terpyridine). In fact 1 also provides the first example of proton-coupled electron transfer involving a sulfur atom. This reaction is notable for the large magnitude of the kinetic isotope effect.

引用

页码：4101 / 4104

页数：4

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