Crystal structure and magnetic properties of Cu(TIM)CuBr4:: An alternating site-alternating exchange chain system

被引：2
|
作者：
Willett, Roger D. [1 ]
Gomez-Garcia, Carlos J.
机构：
[1] Washington State Univ, Dept Chem, Pullman, WA 99164 USA
[2] Univ Valencia, Inst Ciencia Mol, Valencia 46980, Spain
来源：
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS | 2007年 / 316卷 / 02期
关键词：
copper bromide salt; one-dimensional magnetic system; crystal structure; ANTIFERROMAGNETIC INTERACTIONS; BEHAVIOR; CU(II); NI(II);
D O I：
10.1016/j.jmmm.2007.02.152
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The title compound, Cu(TIM)CuBr4 (where TIM is a macrocycle ligand) is a member of the Cu(TIM) MX4 family, which contains linear chain structures with ...Cu...X-M-X...Cu...X-M -... linkages. This chain structure defines an alternating exchange/ alternating site 1d system. For M = Cu, alternating FM/AFM chains are formed with J(FM) > | J(AFM)|. Structural and magnetic data are presented, along with an analysis of the exchange pathways. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：E368 / E370
页数：3
相关论文
共 50 条
  • [11] Crystal Structure and Spin-Singlet State of the LixVOPO4 Insertion Electrode System with Alternating-Bond Chain
    Onoda, Masashige
    Ikeda, Satoshi
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2013, 82 (05)
  • [12] Magnetic properties of Cu(L-aspartato)(H2O)2:: An alternating linear chain antiferromagnet
    Calvo, R
    Passeggi, MCG
    Moreno, NO
    Rao, D
    Barberis, GE
    Cháves, AB
    Torres, BCM
    MAGNETISM, MAGNETIC MATERIALS AND THEIR APPLICATIONS, 1999, 302-3 : 349 - 352
  • [13] MAGNETIC EXCHANGE INTERACTIONS IN THE ALTERNATING COPPER CHAIN CU2(CDTA).4H2O DERIVED FROM SUSCEPTIBILITY AND EPR MEASUREMENTS
    BORRASALMENAR, JJ
    CORONADO, E
    GATTESCHI, D
    GOMEZGARCIA, CJ
    ZANCHINI, C
    JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (16): : 4206 - 4210
  • [14] On the Oxidation of Octamethylenetetrathiafulvalene by CuBr2 - Synthesis, Crystal Structure and Magnetic Properties of (OMTTF)2-[Cu4Br10]
    Beck, Johannes
    de Oliveira, Adriano Bof
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2009, 635 (03): : 445 - 449
  • [15] Crystal Structure and Magnetic Properties of FeSeO3F-Alternating Antiferromagnetic S=5/2 chains
    Hu, Shichao
    Johnsson, Mats
    Law, Joseph M.
    Bettis, Jerry L., Jr.
    Whangbo, Myung-Hwan
    Kremer, Reinhard K.
    INORGANIC CHEMISTRY, 2014, 53 (08) : 4250 - 4256
  • [16] Synthesis, crystal structure, antibacterial properties, and DFT studies of a new organic-inorganic hybrid [4NO2BzT(4Me)PP]2[CuBr4]
    Zhang, Zi-Han
    Huang, Lin
    Li, Yu-Ting
    Hu, Bao-Yi
    Li, Xin-Ran
    Jiang, Yan
    Wang, Zong
    Ni, Chun-Lin
    Liu, Wei
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2025, 769 (01) : 24 - 39
  • [17] The first alternating MnII-MnIII 1D chain: structure, magnetic properties and catalytic oxidase activities
    Ganguly, Sayantan
    Kar, Paramita
    Chakraborty, Maharudra
    Ghosh, Ashutosh
    NEW JOURNAL OF CHEMISTRY, 2018, 42 (12) : 9517 - 9529
  • [18] MAGNETIC-PROPERTIES AND CRYSTAL-STRUCTURE OF A 1D ALTERNATING CHAIN COPPER(II) COMPOUND WITH BRIDGING FUMARATE AND TRANS-OXAMIDATE LIGANDS
    ZHONG, NC
    WEN, XT
    MIAO, FM
    WANG, JL
    POLYHEDRON, 1994, 13 (17) : 2543 - 2548
  • [19] A 1-D alternating copper(II) chain based on three acetate-bridging modes: synthesis, crystal structure, DNA binding and magnetic properties
    Zhao, Chun-Lai
    Xie, Li-Fu
    Li, Bing
    Qiao, Xin
    Xie, Cheng-Zhi
    Bao, Wei-Guo
    Xu, Jing-Yuan
    JOURNAL OF COORDINATION CHEMISTRY, 2016, 69 (14) : 2182 - 2192
  • [20] Spin dynamics in the alternating chain system Li3Cu2SbO6 with defects probed by nuclear magnetic resonance
    Vavilova, E.
    Nishimoto, S.
    Salikhov, T.
    Vasilchikova, T.
    Nalbandyan, V
    Vasiliev, A.
    Zvereva, E.
    PHYSICAL REVIEW B, 2021, 103 (09)
12345