Etch pits morphology on p-hydroxyacetanilide single crystals

被引:6
|
作者
Boldyrev, VV
Vasil'chenko, MA
Shakhtshneider, TP
Naumov, DY
Boldyreva, EV
机构
[1] Russian Acad Sci, Siberian Branch, Inst Solid State Chem, Novosibirsk 630128, Russia
[2] Novosibirsk State Univ, Dept Chem, Novosibirsk 630090, Russia
关键词
feed-back; p-hydroxyacetanilide; hydrogen bonds structure; etching; etch pits;
D O I
10.1016/S0167-2738(97)00223-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The investigation of etch pits on p-hydroxyacetanilide crystals in various solvents has been carried out in order to study the reaction front development during dissolution of molecular crystals. It has been shown that anisotropic development of etch pits coincides with the arrangement of hydrogen bonds in the crystal. The extent of the reaction front anisotropy was less for the solvents with higher donor number, and the shapes of etch pits on the (010) plane changed from elongated to hexagonal.
引用
收藏
页码:869 / 874
页数:6
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