Perfluoroalkanosulfonyl fluoride: A useful reagent for dehydration of aldoximes to nitriles

被引：5
|
作者：
Yan, Zhao-Hua [1 ]
Tian, Huan [1 ]
Zhao, Dong-Dong [1 ]
Jin, Hong-Ai [1 ]
Tian, Wei-Sheng [2 ]
机构：
[1] Nanchang Univ, Coll Chem, Nanchang 330031, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2016年 / 27卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Perfluoroalkanosulfonyl fluoride; Dehydration; Aldoximes; Nitriles; 1,8-Diazabicyclo[5.4.0]undec-7-ene; CONVERSION; EFFICIENT; AMIDES; SYSTEM; CONCISE; OXIMES;
D O I：
10.1016/j.cclet.2015.11.004
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of a variety of aldoximes with perfluoroalkanosulfonyl fluoride in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) in dichloromethane smoothly generated the corresponding nitriles in 70%-95% yields. (C) 2015 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：96 / 98
页数：3
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