A convenient reagent for the conversion of aldoximes into nitriles and isonitriles

被引：18

作者：

Zhang, Wei ^{[1
]}

Lin, Jin-Hong ^{[1
]}

Zhang, Pengfei ^{[2
]}

Xiao, Ji-Chang ^{[1
]}

机构：

[1] Chinese Acad Sci, Univ Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China

[2] Cent South Univ, Xiangya Hosp, Dept Oncol, NHC Key Lab Canc Prote, 87 Xiangya Rd, Changsha 410008, Hunan, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 46期

关键词：

PALLADIUM-CATALYZED CYANATION; HIGHLY EFFICIENT; BECKMANN REARRANGEMENT; PRIMARY AMIDES; DEHYDRATION; ARYL; ISOCYANIDES;

D O I：

10.1039/d0cc00188k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For the dehydroxylation of aldoximes with 4-nitro-1-((trifluoromethyl)sulfonyl)-imidazole (NTSI), slight modifications of reaction conditions resulted in significantly different reaction paths to provide either nitriles or isonitriles. The challenging conversion of aldoximes into isonitriles was achieved under mild conditions.

引用

页码：6221 / 6224

页数：4

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