An unprecedented ten-connected 3D metal-organic framework based on hexanuclear cobalt(II) cluster building blocks

被引：9

作者：

Guo, Zhiyong ^{[1
]}

Su, Shengqun ^{[1
]}

Deng, Ruiping ^{[1
]}

Zhang, Hongjie ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 51卷

基金：

中国国家自然科学基金;

关键词：

Metal-organic framework; Biphenyl-3; 4'; 5-tricarboxylate; (H3BPT); Crystal structure; Free carboxylic acids; Antiferromagnetic interaction; MAGNETIC-PROPERTIES; PENTANUCLEAR; RELAXATION; NETWORK; BINDING; LIGAND; UNITS;

D O I：

10.1016/j.inoche.2014.10.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 3D metal-organic framework (MOF), [Co-3(mu(3)-OH)(mu(2)-H2O)(BPT)(HBPT)(DMF)(2)] (DMF)(H2O) (1) (DMF = N, N'-dimethylformamide) has been synthesized by self-assembly of cobalt(II) oxide and biphenyl-3, 4', 5-tricarboxylate (H3BPT) under solvothermal reaction. Compound 1 displays unique (2,3,10)-connected trinodal connected topology. Besides, 1 represents a rare example of MOF possessing free carboxylic acids. In addition, the magnetic property of the compound is investigated. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：9 / 12

页数：4

共 50 条

[21] An unprecedented (3,4)-connected self-penetrating metal-organic framework
Hua, Rong
Wu, Xiao Liu
Li, Jin Ying
Shi, Lei
Luo, Feng
INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 39 : 90 - 93
[22] A 3D Cd(II) metal-organic framework with trinuclear metal cluster: Hydrothermal synthesis, structure and luminescent property
Xu, Han
Zheng, He-Gen
INORGANIC CHEMISTRY COMMUNICATIONS, 2015, 60 : 95 - 96
[23] A (3,12)-connected 3D metal-organic framework based on nanosized octanuclear zinc clusters
Lan, Ya-Qian
Li, Shun-Li
Shao, Kui-Zhan
Wang, Xin-Long
Du, Dong-Ying
Su, Zhong-Min
Wang, De-Jun
CRYSTAL GROWTH & DESIGN, 2008, 8 (10) : 3490 - 3492
[24] A 12-connected metal-organic framework constructed from an unprecedented cyclic dodecanuclear copper cluster
Zhang, Huan
Lu, Ying
Zhang, Zhiming
Fu, Hai
Li, Yangguang
Volkmer, Dirk
Denysenko, Dmytro
Wang, Enbo
CHEMICAL COMMUNICATIONS, 2012, 48 (58) : 7295 - 7297
[25] An eight-connected 3D lead(II) metal-organic framework with octanuclear lead(II) as a secondary building unit: synthesis, characterization and luminescent property
Yang, En-Cui
Li, Jian
Ding, Bin
Liang, Qing-Qing
Wang, Xiu-Guang
Zhao, Xiao-Jun
CRYSTENGCOMM, 2008, 10 (02) : 158 - 161
[26] An acs-Type Metal-Organic Framework with an Unprecedented Undecanuclear Copper Cluster as Secondary Building Unit
Hu, Sheng
Yu, Fang-Yong
Zhang, Peng
Zhou, Ai-Ju
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (23) : 3669 - 3673
[27] Phosphinic Acid Based Linkers: Building Blocks in Metal-Organic Framework Chemistry
Hynek, Jan
Brazda, Petr
Rohlicek, Jan
Londesborough, Michael G. S.
Demel, Jan
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (18) : 5016 - 5019
[28] An Asymmetric Supercapacitor Based on a Non-Calcined 3D Pillared Cobalt(II) Metal-Organic Framework with Long Cyclic Stability
Sanati, Soheila
Abazari, Reza
Morsali, Ali
Kirillov, Alexander M.
Junk, Peter C.
Wang, Jun
INORGANIC CHEMISTRY, 2019, 58 (23) : 16100 - 16111
[29] Structure and bifunctional electrocatalytic activity of a novel 3D framework based on dimeric monocopper-substituted polyoxoanions as ten-connected linkages
Li, Shaobin
Zhu, Wei
Ma, Huiyuan
Pang, Haijun
Liu, Heng
Yu, Tingting
RSC ADVANCES, 2013, 3 (25): : 9770 - 9777
[30] Synthesis of Polycarboxylate Rhodium(II) Metal-Organic Polyhedra (MOPs) and their use as Building Blocks for Highly Connected Metal-Organic Frameworks (MOFs)
Grancha, Thais
Carne-Sanchez, Arnau
Zarekarizi, Farnoosh
Hernandez-Lopez, Laura
Albalad, Jorge
Khobotov, Akim
Guillerm, Vincent
Morsali, Ali
Juanhuix, Judith
Gandara, Felipe
Imaz, Inhar
Maspoch, Daniel
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (11) : 5729 - 5733

← 1 2 3 4 5 →